Refined relationship between the position of the fundamental OH stretching and the first overtones for clays     

S.?PetitEmail author  A.?Decarreau  F.?Martin  R.?Buchet 《Physics and Chemistry of Minerals》2004,31(9):585-592

The aim of this paper is to determine a relationship between the wavenumbers of the first OH-stretching overtones (W_2OH) and the wavenumbers of the OH-stretching fundamentals (W_OH) to help to interpret the near-infrared (NIR) spectra. The first overtone (2OH) bands appear at wavenumbers less than twice those of the fundamental bands (OH), due to the anharmonic character of vibrations, X = W_2OH/2 - W_OH, with X being the anharmonicity constant. Talc samples with various crystal chemistries are used to solve the equation and the experimental data are well fitted with X = –85.6 cm^–1. As far as the authors are aware, it is the first time that the anharmonicity constant for the OH-stretching vibrations is determined for phyllosilicates. The anharmonicity constant remains almost unchanged for several types of clay samples. Therefore the relation, established from talc samples because their absorption bands are narrow and their wavenumber range of OH vibrations is wide, can be used for any other clay minerals.  相似文献   

柴达木盆地西部地区断裂类型及油气勘探意义   总被引：5，自引：1，他引：4       下载免费PDF全文

王亚东  方小敏  高军平  刘栋梁  张跃中  张伟林 《地质科学》2009,44(3):957-965

为研究柴西地区油气成藏及其与青藏高原隆升的关系,我们借助生长断层定性和定量分析,总结出该区断裂在演化上总体可归纳为两个主要形成时期和4种表现形式：早期形成时期(E1＋2?N),中生代以来开始活动,多数终止于下油砂山组末(约14.9 Ma); 晚期形成时期(N?Q),上油砂山组开始活动,狮子沟组(约8.2 Ma)以来活动尤为剧烈,持续至今。在形式上主要表现为限于下或上构造层的生长断层; 贯穿下、上构造层的生长断层和后期断层4类。柴西地区的这种断裂构造特征,与青藏高原的分阶段隆升相对应,控制着该区的油气运移、成藏、保存及改造,对我们在柴西地区的油气勘探工作具有重大意义。  相似文献   

关于鱼的生长方程的研究──Ⅱ.估计参数的一种新方法   总被引：2，自引：0，他引：2  

赵维谦 《海洋与湖沼》1994,25(5):499-504

目前描述鱼的体重生长的方程主要有（１）ｗ＝ｗ∞［１－ｅ＾－ｋ（ｔ－ｔ０）］＾３，和作者对该方程推广而导出的方程（２）ｗ＝ｗ∞［１－ｅ＾－ｋ（ｔ－ｔ０）］＾ｒ，本文对基于这两个方程的４种参数估计法，指出了其不足之处，并提出了一种估计参数的新方法－搜寻逼近法。该方法比前４种方法具有更好的拟合优度，通过实例计算得到进一步的证实。此外，还外鱼的样本资料的处理作了论述。这对更好的掌握鱼的生长规律，进而合理利  相似文献   

赣南地区寒武纪高滩组碎屑锆石U-Pb年龄和Hf同位素特征及地质意义     

马虎超  徐文坦  钟康惠  龚安州  郭坤一  杨川 《新疆地质》2019,(2):270-277

寒武纪高滩组广泛分布于赣南武功山-雩山地区,主体为一套浅变质砂岩夹板岩的复理石建造。为分析其物源,并对源区地壳生长和构造演化提供约束,本文对采自高滩组的变长石石英杂砂岩进行了LA-ICP-MS碎屑锆石U-Pb年代学和Hf同位素研究。锆石U-Pb年龄数据显示2 500 Ma、1 100~900 Ma和900~700 Ma 3个主要年龄峰值。2 500 Ma的年龄峰值代表了新太古代末期—古元古代的古陆核生长事件。1 100~900 Ma和900~700 Ma两个峰最显著,表明Rodinia超大陆聚合裂解在华南地区的响应,为该区寒武纪地层提供了主要物源。此外,3 003 Ma锆石年龄的捕获说明,华夏地块可能存在太古宙地壳基底。Hf同位素数据表明,源区锆石结晶多为古老地壳组分部分熔融产生的岩浆。结合锆石年龄数据分析认为,华南地区存在强烈的新元古代岩浆活动,该时期岩浆活动主要是古老地壳物质的再循环。  相似文献   

Green growth machines? Competing discourses of urban development in Playa Vista,California     

Christine L. Jocoy 《Urban geography》2018,39(3):388-412

Playa Vista is a massive mixed-use development built on coastal wetlands in west Los Angeles. Its land use story illustrates how strategically constructed discourses shape contested urban spaces. Through an analysis of newspaper reporting and government documents, this paper traces how pro-Playa Vista interests changed their growth discourses rationalizing the development between 1979 and 2015. Findings suggest that pro-growth coalitions are resilient when they modify their discourses to negotiate new regulatory and political contexts, specifically pursuing sustainability fixes. They are not dogmatic in their adherence to orthodoxies of private property rights and “highest and best use” of land but rather continually reconstruct growth discourses incorporating enough of the values of their opponents (i.e. “green” values such as growth management and smart growth) that some environmental and homeowner citizens’ groups join the growth coalition, forming a “green growth machine” that not only profitably builds on the land but finances ecological restoration.  相似文献   

红阳猕猴桃种植基地自动站温度对其生长季的影响   总被引：2，自引：1，他引：1  

池再香  张锦  肖钧  吴丹  龚雪芹  李贵琼 《气象科学》2018,38(2):258-263

利用贵州西部发耳、米箩、猴场、蟠龙、鸡场、顺场、杨梅、勺米共8个红阳猕猴桃基地2013—2015年物候期观测资料、猴场基地红阳猕猴桃果实生长期生长速率及其产量资料以及各基地2005—2015年温度资料,运用C值逼近法和决定系数(R~2)最大化法拟合红阳猕猴桃果实生长曲线,采用相关性分析方法,分析了温度对红阳猕猴桃物候期的影响。结果表明,红阳猕猴桃各个物候期出现的时间及其日数与温度变化具有一致性,但各个物候期对温度的响应表现出不一致。红阳猕猴桃开花期对平均温度、平均最高温度的响应最为明显,其相关性达到极显著水平(p0.001)。平均最高温度对果实生长期日数的影响呈负相关性,其相关性达到极显著水平(p0.005)。果实生长量的75.69%受时间影响,24.31%受气候因素影响。  相似文献   

Sublethal effects of a chlorinated and heated effluent on the physiology of the mussel,Mytilus edulis L.: A reduction in fitness for survival?     

《Marine pollution bulletin》2014,78(1-2):123-131

Coastal power stations entrain large volumes of cooling water, requiring biocidal treatment to prevent biological fouling. Discharged effluent is both heated and contaminated with residual traces of biocide and so it is necessary to quantify the impacts of this discharge. Cooling water from Heysham 2 nuclear power station, NW England, UK, is discharged to the intertidal area, via a culvert (to minimise erosion and maximise dilution and dispersion by directing the effluent into the receiving water at all states of the tide) within which the effluent is contained at low water. The culvert and surrounding coastal area support a population of blue mussels (Mytilus edulis). Mussel health was determined along a gradient of exposure, using three physiological indices: Scope for Growth, Gonad Mantle Index and Somatic Condition Index (K Factor). The Mussels within the culvert exhibited reduced physiological index values compared to an external site. A trend was identified down the length of the culvert, representing a gradient of exposure and indicating a potential negative effect on growth and reproductive output.  相似文献   

Growth patterns and dynamics of mud cracks at different diagenetic stages and its geological significance     

Zhen-yu ZHAO  Yan-ru GUO  Yan WANG  Hong LIU  Qing ZHANG 《国际泥沙研究》2014,29(1):82-98

This paper discusses the growth stages,spatial structures,quantitative fitting relationships among various parameters,growth patterns and influencing factors of mud cracks by field survey,core observation and SEM analysis.The study shows that:(1) Mud crack growth can go through three stages,i.e.the syndiagenetic stage,the burial diagenetic stage(including early diagenetic stage,middle-late diagenetic stage) and the epidiagenetic stage.(2) Quantitative fitting relationships among various parameters allow a great significance to describe the spatial structure,the regional distribution and the growth environment of mud cracks.(3) Mud crack growth has three models,such as the unilateral growth model including the linear growth pattern,the curvilinear growth pattern and the bifurcation growth pattern,the multilateral growth model including the inteisectional growth pattern,the join growth pattern and the dispersed growth pattern,and the mixed growth model including the combination of any patterns listed above.(4) Modern mud crack growth usually undergoes four stages.Sand beds in sand-mud rhythmic strata can play a lubricative role on crack growth and provide enough sandy deposits for filling cracks.(5) Mud crack growth usually produces bifurcation and bifurcation angles which are mostly 120° or 90° that are related to sediment heterogeneity and released energy.(6)Factors affecting mud crack growth cover many aspects:clay content and salinity can control the number of mud cracks in different areas;terrain can control mud crack morphology;and different sedimentary cycles can control the growth patterns and filling models of mud cracks.  相似文献   

冰雷达探测研究南极冰盖的进展与展望   总被引：3，自引：0，他引：3  

崔祥斌  孙波  田钢  蒋芸芸  张向培  郭井学  唐学远 《地球科学进展》2009,24(4):392-402

南极冰盖是地球上最大的陆缘冰体,其物质收支和稳定性对全球气候变化和海平面升高有重要的影响。冰雷达,或称无线电回波探测,是冰川学家调查南极冰盖冰下特征的主要方法。在过去的50年里,冰雷达被广泛用于测量冰盖厚度、内部构造和冰下地貌,这些参数是计算冰盖体积和物质平衡、重建过去冰雪积累和消融率以及冰盖动力和沉积过程的基础。现在,冰雷达测量覆盖了南极绝大部分区域,极大地提升了人们对南极冰盖和全球系统间相互作用的理解。首先,简要介绍了冰雷达及其技术发展,然后着重评述了冰雷达在探测研究南极冰盖厚度和冰下地形、内部反射层、冰下湖和冰下水系、冰床粗糙度以及冰晶组构上的进展。最后,对未来冰雷达探测研究南极冰盖的前景进行了展望,并给出我国的现状。
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碳酸盐生物沉积作用的研究现状与展望   总被引：6，自引：2，他引：4  

李为  刘丽萍  曹龙  余龙江 《地球科学进展》2009,24(6):597-605

碳酸盐矿物是地球上最丰富的矿物之一,碳酸盐沉积在许多地质过程中起着非常重要的作用.生物沉积碳酸盐的现象在自然界普遍存在,其中又以生物沉积碳酸钙(CaCO3)为主.生物从周围环境中选择性地吸取元素,在严格的生物控制下,组装成功能化的碳酸盐结构;生物也可以通过改变周围的环境诱导碳酸盐的沉积或自身参与碳酸盐的沉积.不同生物对碳酸盐沉积的作用扣机理不同,综述了海洋动植物、藻类生物、菌类生物对碳酸盐的沉积作用及其机理以及实验室模拟调控CaCO3生物矿化方面的一些研究成果和研究现状,提出未来亟待解决的一些重要问题,并指出生物沉积碳酸盐研究所具有的巨大应用前景.  相似文献